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Crotonic acid(CAS#107-93-7)

Chemical Property:

Molecular Formula C4H6O2
Molar Mass 86.09
Density 1.027 g/mL at 25 °C (lit.)
Melting Point 70-72 °C (lit.)
Boling Point 180-181 °C (lit.)
Flash Point 190°F
JECFA Number 1371
Water Solubility 94 g/L (25 ºC)
Solubility H2O: soluble
Vapor Presure 0.19 mm Hg ( 20 °C)
Vapor Density 2.97 (vs air)
Appearance Crystalline Flakes
Color White to light yellow
Merck 14,2597
BRN 1719943
pKa 4.69(at 25℃)
PH 3 (10g/l, H2O, 20℃)
Storage Condition Store below +30°C.
Explosive Limit 15.1%, 171°F
Refractive Index 1.4228
Physical and Chemical Properties Trait: monoclinic needle-like or prismatic crystal.

melting point 71.4~71.7 ℃

boiling point 184.7 ℃

relative density 1.108

refractive index 1.4228

soluble in ethanol, ether and acetone.

Use Trans-butenoic acid is mainly used for the preparation of synthetic resins, plasticizers, drugs, but also for other organic synthesis

Product Detail

Product Tags

Risk Codes R21/22 – Harmful in contact with skin and if swallowed.
R34 – Causes burns
R50/53 – Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R36/37/38 – Irritating to eyes, respiratory system and skin.
Safety Description S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
S37/39 – Wear suitable gloves and eye/face protection
UN IDs UN 2823 8/PG 3
WGK Germany 3
RTECS GQ2900000
HS Code 29161940
Hazard Class 8
Packing Group III
Toxicity LD50 orally in rats: 1.0 g/kg (Smyth, Carpenter)

 

Introduction

Trans-butenedioic acid (cis-9,10-dihydroxy-9,10-dimethyl-1,2-dihydro-5,6-cyclohexene-1,2-dicarboxylic acid) is an organic compound.Properties:Trans-butenedioic acid is a white crystalline powder that is soluble in water and organic solvents. It has good thermal stability and chemical stability. Trans-butenedioic acid can undergo a dehydration reaction under acidic conditions to form trans-butenedioic anhydride.Uses:Preparation:There are usually two methods for the preparation of trans-butenedioic acid:Oxidize butenedioic acid with vanadium peroxide acid, followed by hydrolysis to obtain trans-butenedioic acid.Perform an acid-catalyzed high-temperature dehydration reaction on butenedioic acid to obtain trans-butenedioic anhydride, followed by reduction and hydrolysis to obtain trans-butenedioic acid.Safety Information:Trans-butenedioic acid is an organic compound with certain toxicity and should avoid direct contact with the skin or inhalation of its dust.During use and storage, fire and explosion protection should be observed, and contact with oxidizers and strong acids should be avoided.Waste that has not been professionally treated should be handled according to local regulations to avoid environmental pollution.


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