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Aniline(CAS#62-53-3)

Chemical Property:

Molecular Formula C6H7N
Molar Mass 93.13
Density 1.022 g/mL at 25 °C (lit.)
Melting Point -6 °C (lit.)
Boling Point 184 °C (lit.)
Flash Point 76 °C
Water Solubility 36 g/L (20 ºC)
Solubility water: soluble
Vapor Presure 0.7 mm Hg ( 25 °C)
Vapor Density 3.22 (185 °C, vs air)
Appearance Liquid
Specific Gravity 1.021
Color APHA: ≤250
Odor Sweet, amine-like odor detectable at 0.6 to 10 ppm
Exposure Limit TLV-TWA skin 2 ppm (~8 mg/m3) (ACGIH),5 ppm (~19 mg/m3) (MSHA, OSHA, andNIOSH); IDLH 100 ppm (NIOSH).
Merck 14,659
BRN 605631
pKa 4.63(at 25℃)
PH 8.8 (36g/l, H2O, 20℃)
Storage Condition 2-8°C
Stability Stable. Incompatible with oxidizing agents, bases, acids, iron and iron salts, zinc, aluminium. Light sensitive. Combustible.
Explosive Limit 1.2-11%(V)
Refractive Index n20/D 1.586(lit.)
Physical and Chemical Properties Colorless oily flammable liquid with strong odor. Melting Point -6.3 ℃, boiling point 184 ℃,68.3 ℃(1.33kPa), relative density 1.0217(20/4 ℃), refractive index 1.5863, Flash Point (Open Cup) 70 ℃, spontaneous ignition point 770. In the open air or light will gradually turn brown. Can be volatilized with water vapor. Aniline can be miscible with ethanol, ether, chloroform and many other organic solvents. The solubility (weight percentage) of aniline in water is 3.7% at 30 °c, 4.2% at 50 °c, and 110 at 8.0% °c. There are alkaline, can be generated with hydrochloric acid hydrochloride, and sulfuric acid sulfate.
Use Aniline is an important intermediate. The more important products produced by aniline were 300. There are about 80 aniline manufacturers in the world, with an annual total production capacity of more than 2.7 million t/a and an output of about 2.3 million t. The main consumption field is MDI, in 2000, its consumption accounted for about 84% of the total consumption of aniline. Aniline is mainly consumed in MDI, dye industry, rubber additives, pharmaceuticals, pesticides and organic intermediates.

Product Detail

Product Tags

Risk Codes R23/24/25 – Toxic by inhalation, in contact with skin and if swallowed.
R40 – Limited evidence of a carcinogenic effect
R41 – Risk of serious damage to eyes
R43 – May cause sensitization by skin contact
R48/23/24/25 -
R50 – Very Toxic to aquatic organisms
R68 – Possible risk of irreversible effects
R48/20/21/22 -
R39/23/24/25 -
R11 – Highly Flammable
Safety Description S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27 – Take off immediately all contaminated clothing.
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S46 – If swallowed, seek medical advice immediately and show this container or label.
S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
S63 -
S36/37 – Wear suitable protective clothing and gloves.
S16 – Keep away from sources of ignition.
UN IDs UN 1547 6.1/PG 2
WGK Germany 2
RTECS BW6650000
FLUKA BRAND F CODES 8-9
TSCA Yes
HS Code 2921 41 00
Hazard Class 6.1
Packing Group II
Toxicity LD50 orally in rats: 0.44 g/kg (Jacobson)

 

Introduction

Aniline is an organic compound, and the following is an introduction to the properties, uses, preparation methods and safety information of aniline:Quality:- Aniline is a colorless liquid with a strong pungent odor at room temperature.- Soluble in water and organic solvents, with strong alkalinity.- Aniline is a strong reducing agent that reacts violently with oxidants such as oxygen and chlorine.- Prone to oxidation and gradually darken when exposed to air.Use:- It is an important raw material for the production of synthetic fibers, rubber antioxidants, etc.Preparation method:- Aniline is usually prepared by the reduction of phenyl nitrate or the epoxidation of aromatic amines.- Phenylnitric acid reduction is the most common method of preparing aniline, which is obtained by reacting phenyl nitric acid with a reducing agent such as sulfite.Safety Information:- Aniline is highly irritating and can cause damage to the skin, eyes, and respiratory system, so contact should be avoided.- Long-term exposure to aniline can cause damage to the central nervous system and hematopoietic system.- Aniline is a carcinogen that may be associated with the development of leukemia and other malignant tumors.- Proper safety measures must be taken when handling aniline, such as wearing protective gloves, goggles, and protective clothing, to ensure safe handling and good ventilation.


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