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Chlorobenzene(CAS#108-90-7)

Chemical Property:

Molecular Formula C6H5Cl
Molar Mass 112.56
Density 1.106 g/mL at 25 °C (lit.)
Melting Point -45 °C (lit.)
Boling Point 132 °C (lit.)
Flash Point 75°F
Water Solubility 0.4 g/L (20 ºC)
Solubility water: soluble0.207 g/L at 20°C
Vapor Presure 11.8 mm Hg ( 25 °C)
Vapor Density 3.86 (vs air)
Appearance Liquid
Color APHA: ≤30
Odor Almond like odour
Exposure Limit TLV-TWA 75 ppm (~345 mg/m3) (ACGIH,MSHA, OSHA, and NIOSH); IDLH2400 ppm.
Maximum wavelength(λmax) ['λ: 288 nm Amax: 1.0',
, 'λ: 290 nm Amax: 0.40',
, 'λ: 300 nm Amax: 0.05',
, 'λ: 325
Merck 14,2121
BRN 605632
Storage Condition 2-8°C
Stability Stable. Incompatible with oxidizing agents. Flammable. Attacks some types of plastics, rubber and coatings.
Explosive Limit 1.3-11%(V)
Refractive Index n20/D 1.524(lit.)
Physical and Chemical Properties characteristics of colorless transparent, volatile liquid, almond flavor.
boiling point 132.2 ℃
freezing point -45.6 ℃
relative density 1.1004
refractive index 1.5248
flash point 28 ℃
solubility is soluble in most organic solvents, insoluble in water.
Use Used as dyes, pharmaceuticals, pesticides, organic synthesis intermediates and solvents

Product Detail

Product Tags

Risk Codes R10 – Flammable
R20 – Harmful by inhalation
R51/53 – Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R40 – Limited evidence of a carcinogenic effect
R39/23/24/25 -
R23/24/25 – Toxic by inhalation, in contact with skin and if swallowed.
R11 – Highly Flammable
Safety Description S24/25 – Avoid contact with skin and eyes.
S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
S36/37 – Wear suitable protective clothing and gloves.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S16 – Keep away from sources of ignition.
S7 – Keep container tightly closed.
UN IDs UN 1134 3/PG 3
WGK Germany 2
RTECS CZ0175000
FLUKA BRAND F CODES 3-10
TSCA Yes
HS Code 29039190
Hazard Class 3
Packing Group III
Toxicity LD50 orally in Rabbit: 2000 – 4000 mg/kg

 

Introduction

Chlorobenzene is an organic compound. It is the product of the substitution of a hydrogen atom on the benzene ring by a chlorine atom. The following is a detailed introduction to the properties, uses, preparation methods and safety information of chlorobenzene:Quality:- Appearance: Colorless liquid or white crystals.- Solubility: Soluble in organic solvents such as ethanol and ether, insoluble in water.- Chlorobenzene exists in a variety of isomers, such as O-chlorobenzene, M-chlorobenzene, and p-chlorobenzene.Use:- Industrial Use: Chlorobenzene is widely used in organic synthesis reactions and industrial production, where it can be used as a solvent, antimicrobial, flame retardant, pesticide, pickling agent, etc.- Laboratory Uses: Chlorobenzene can be used as a solvent and reaction intermediate for organic synthesis experiments.Preparation method:The main preparation methods of chlorobenzene are as follows:- Direct chlorination: Chlorobenzene is obtained by heating benzene with chlorine gas. For example: C6H6 Cl2 → C6H5Cl HCl.- Carbon chlorination: Chlorobenzene is obtained by reacting benzene and carbon tetrachloride in the presence of aluminum chloride catalysts. For example: C6H6 CCl4 → C6H5Cl HCCl3.Safety Information:- Chlorobenzene has certain toxicity and is harmful to the human body and the environment. After entering the human body, it can cause health hazards through inhalation, ingestion or absorption through the skin.- Long-term or heavy exposure to chlorobenzene can lead to damage to organs such as the central nervous system, liver, and kidneys, leading to health problems.- When using chlorobenzene, take personal protective measures, such as wearing protective gloves, face shields, and protective glasses, to ensure a well-ventilated working environment. Attention should be paid to observing relevant safety operating procedures.


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