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Methacrylic acid(CAS#79-41-4)

Chemical Property:

Molecular Formula C4H6O2
Molar Mass 86.09
Density 1.015 g/mL at 25 °C (lit.)
Melting Point 12-16 °C (lit.)
Boling Point 163 °C (lit.)
Flash Point 170°F
Water Solubility 9.7 g/100 mL (20 ºC)
Vapor Presure 1 mm Hg ( 20 °C)
Vapor Density >3 (vs air)
Appearance Liquid
Color Clear
Odor Repulsive
Exposure Limit TLV-TWA 20 ppm (~70 mg/m3) (ACGIH).
Merck 14,5941
BRN 1719937
pKa pK1:4.66 (25°C)
PH 2.0-2.2 (100g/l, H2O, 20℃)
Storage Condition Store at +15°C to +25°C.
Stability May be stabilized by the addition of MEHQ (Hydroquinone methyl ether, ca. 250 ppm) or hydroquinone. In the absence of a stabilizer this material will readily polymerize. Combustible.
Sensitive Moisture & Light Sensitive
Explosive Limit 1.6-8.7%(V)
Refractive Index n20/D 1.431(lit.)
Physical and Chemical Properties Character: colorless transparent liquid at room temperature.
melting point 14 ℃
boiling point 159~163 ℃
relative density 1.0153
refractive index 1.4314
flash point 77 ℃
solubility, ethanol and most organic solvents.
Use Used in the manufacture of coatings, insulating materials, adhesives and ion exchange resins

Product Detail

Product Tags

Hazard Symbols C – Corrosive
Risk Codes R21/22 – Harmful in contact with skin and if swallowed.
R35 – Causes severe burns
R37 – Irritating to the respiratory system
R20/21/22 – Harmful by inhalation, in contact with skin and if swallowed.
Safety Description S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
UN IDs UN 2531 8/PG 2
WGK Germany 1
RTECS OZ2975000
TSCA Yes
HS Code 2916 13 00
Hazard Class 8
Packing Group II
Toxicity LD50 orally in Rabbit: 1320 mg/kg

 

Introduction

Methyl methacrylate (MMA) is a colorless liquid with a pungent odor. The following is an introduction to the properties, uses, preparation methods and safety information of methacrylic acid:Quality:Appearance: Colorless liquidDensity: 0.94 g/cm³Soluble: miscible with water and soluble in many organic solvents.Use:MMA is widely used as a monomer in the chemical industry for the polymerization of polymethyl methacrylate (PMMA).PMMA is widely used in optical fibers, optics, medical devices, building materials and handicrafts.MMA can also be used to polymerize acrolein resins and vinylate copolymers.Preparation method:The preparation of MMA can be done by acrylonitrile hydrogenation, isobutenone hydrogenation and methanol esterification. Among them, acrylonitrile hydrogenation is the main production method, through the reaction of acrylonitrile and hydrogen in the presence of a catalyst to obtain methacrylic acid.Safety Information:MMA is irritating and can cause irritation and burning sensation when it comes into contact with the skin and eyes. Direct contact with skin and eyes should be avoided and appropriate protective gloves and glasses should be worn.Long-term or heavy exposure to MMA can cause damage to the skin, eyes, and respiratory tract. Maintain good ventilation during operation and avoid inhaling its vapors.MMA is flammable and should be stored in a cool, dry place, away from fire and high temperatures.


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