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Citric acid(CAS#77-92-9)

Chemical Property:

Molecular Formula C6H8O7
Molar Mass 192.12
Density 1.67 g/cm3 at 20 °C
Melting Point 153-159 °C (lit.)
Boling Point 248.08°C (rough estimate)
Flash Point 100 °C
JECFA Number 218
Water Solubility soluble in Water (1174g/L at 10°C, 1809g/L at 30°C, 3825g/L at 80°C).
Solubility Soluble in water 750g/L (20°C), ethanol, ether, insoluble in benzene, slightly soluble in chloroform
Vapor Presure <0.1 hPa (20 °C)
Vapor Density 7.26 (vs air)
Appearance White crystalline powder
Color White
Odor Odorless
Maximum wavelength(λmax) ['λ: 260 nm Amax: 0.20',
, 'λ: 280 nm Amax: 0.10']
Merck 14,2326
BRN 782061
pKa 3.14(at 20℃)
PH 3.24(1 mM solution);2.62(10 mM solution);2.08(100 mM solution);
Storage Condition 2-8°C
Stability Stable. Incompatible with bases, strong oxidizing agents, reducing agents, metal nitrates.
Sensitive Hygroscopic
Explosive Limit 8%, 65°F
Refractive Index 1.493~1.509
MDL MFCD00011669
Physical and Chemical Properties Relative density 1.542, melting point 153 ℃ (water loss), refractive index 1.493~1.509
colorless translucent crystals or white particles, or white crystalline powder, often containing a molecule of crystal water, odorless, extremely sour taste, soluble in water, alcohol and ether. Its calcium salt is more soluble in cold water than hot water, and this property is often used to identify and isolate citric acid. Anhydrous citric acid can be obtained by controlling the appropriate temperature during crystallization. The aqueous solution was acidic. It is slightly weathered in dry air and deliquescent in moist air. Above 175 deg C and carbon dioxide free water.
Use Used as experimental reagents, chromatographic analysis reagents and biochemical reagents, also used in the preparation of buffer. It is used in the food industry in particular as an acidifying agent, a PH buffering agent, and together with other compounds as a preservation agent. In the detergent industry, it is an ideal substitute for phosphate. Boiler chemical cleaning pickling agent, boiler chemical cleaning rinsing agent. It is mainly used as a sour agent for food, and is also used for the preparation of medical coolants and detergents?

Product Detail

Product Tags

Risk Codes R41 – Risk of serious damage to eyes
R36/37/38 – Irritating to eyes, respiratory system and skin.
R36/38 – Irritating to eyes and skin.
R37/38 – Irritating to respiratory system and skin.
R34 – Causes burns
R36 – Irritating to the eyes
R35 – Causes severe burns
R61 – May cause harm to the unborn child
R60 – May impair fertility
Safety Description S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S39 – Wear eye / face protection.
S37/39 – Wear suitable gloves and eye/face protection
S24/25 – Avoid contact with skin and eyes.
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36 – Wear suitable protective clothing.
S53 – Avoid exposure – obtain special instructions before use.
UN IDs UN 1789 8/PG 3
WGK Germany 1
RTECS GE7350000
FLUKA BRAND F CODES 9
TSCA Yes
HS Code 2918 14 00
Toxicity LD50 in mice, rats (mmol/kg): 5.0, 4.6 i.p. (Gruber, Halbeisen)

 

Introduction

Citric acid is an organic acid. It is a colorless and odorless crystalline powder that dissolves in water and ethanol.The main uses of citric acid are as follows:Detergents: They have cleansing and dissolving effects and are commonly used in products such as detergents, hand sanitizers, and dish soaps.There are two main common methods for making citric acid:By fermentation: Using the fermentation of citric acid bacteria, substances containing sucrose or starch (such as molasses, malt, etc.) are fermented, and finally citric acid is extracted and crystallized.Through chemical synthesis: Citric acid is synthesized by chemical reactions, and commonly used raw materials include methanol, ethylene and oxidants.Citric acid is generally safe in normal doses, but excessive intake may cause stomach pain, vomiting, diarrhea and other digestive discomforts.When using citric acid, the correct method and dosage should be followed and must not be abused.Citric acid is a non-flammable substance, but it may decompose and release toxic gases at high temperatures, so contact with strong oxidants should be avoided.


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