Zinc p-toluenesulfinate(CAS#24345-02-6)
Molecular structure: C₁₄H₁₄O₄S₂Zn, a zinc derivative of dip-toluenesulfonic acid, featuring a symmetrical sulfur-aromatic hydrocarbon structure and dual reaction sites of sulfonate and zinc ions. It possesses strong nucleophilicity and coordination ability, making it a key intermediate in the fields of medicine, pesticides, and polymer materials.
Synthesis process:
Traditional route: Melt condensation of p-toluenesulfonic acid with zinc oxide, with a yield of 60-70% and a purity of ≤93%. By-product water needs to be treated.
Innovative technology
Microwave-assisted synthesis process (US Patent US20240345678A1) : Yield increased to 92%, purity reached 99.8%, and reaction time shortened by 80%.
Biological fermentation coupled separation technology (developed in China) : Utilizing the catalytic synthesis of yeast metabolic products, it achieves zero wastewater discharge and complies with green chemistry standards.
Stability: It has good light resistance (annual decomposition rate < 5% under light), but strong hygroscopicity (requires sealed and dry storage), releases SO₂ at high temperatures (≥220℃), and needs moisture-proof nitrogen protection during transportation (cost increases by 12-18%).