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Ethyl cinnamate(CAS#103-36-6)

Chemical Property:

Molecular Formula C11H12O2
Molar Mass 176.21
Density 1.049 g/mL at 20 °C (lit.)
Melting Point 6-8 °C (lit.)
Boling Point 271 °C (lit.)
Specific Rotation(α) 1.559-1.561
Flash Point >230°F
JECFA Number 659
Water Solubility insoluble
Solubility It is miscible with ethanol and ether and insoluble in water.
Vapor Presure 6Pa at 20℃
Appearance Colorless liquid
Color Clear colorless to pale yellow
Merck 14,2299
BRN 1238804
Storage Condition 2-8°C
Stability Stable. Incompatible with strong oxidizing agents, acids, bases, reducing agents. Combustible.
Sensitive Sensitive to light
Refractive Index n20/D 1.558(lit.)
MDL MFCD00009189
Physical and Chemical Properties Almost colorless transparent oily liquid, with a light and lasting aroma of cinnamon and strawberry and a sweet aroma of honey. No optical rotation, melting point 12 ℃, boiling point 272 ℃, flash point 93.5 ℃. Miscible in ethanol, ether and most non-volatile oils, a few do not dissolve in glycerol and water. Slightly soluble in propylene glycol. Natural products are found in styrax, galangal oil, etc.
Use Is an important Flavor and Fragrance Intermediates, also used as pharmaceutical, food additive intermediates

Product Detail

Product Tags

Risk Codes R20 - Harmful by inhalation
R22 - Harmful if swallowed
Safety Description S23 - Do not breathe vapour.
S24/25 - Avoid contact with skin and eyes.
WGK Germany 1
RTECS GD9010000
TSCA Yes
HS Code 29163990
Toxicity The acute oral LD50 value in rats was reported as 7.8 g/kg (7.41-8.19 g/kg) (Russell, 1973). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Russell, 1973).

 

Introduction

Slightly smell of cinnamon. Polymerization is easy to occur under the action of light and heat. Hydrolysis occurs under the action of caustic. It is miscible with ethanol and ether and insoluble in water. Low toxicity, half lethal dose (rat, oral) 400mg/kg.

Product Name and CAS Number

Ethyl cinnamate Ethyl 3 phenylpropenoate | CAS 103 36 6

One Line Sourcing Position

High purity Ethyl cinnamate for flavor and fragrance formulations and UV curing monomer applications.

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Specification

Purity by GC: 99.0 percent minimum, typical batch 99.3 to 99.6 percent
Appearance: Colorless to pale yellow clear liquid
Odor: Sweet balsamic, fruity with honey and cinnamon like notes
Density at 25 deg C: 1.045 to 1.050 g per mL
Refractive index nD20: 1.558 to 1.562
Acid value: 1.0 mg KOH per g maximum
Water content: 0.10 percent maximum
Assay by GC: 98.5 to 101.0 percent on anhydrous basis
Heavy metals: Less than 10 ppm
Stock Status: In Stock in US warehouse and China hub

Available Quantity and Lead Time

Regular supply: 500 g to 20 metric tons per shipment
Lead time: 2 to 5 days for standard packaging; bulk orders require 7 to 10 days

Document Support

COA SDS HPLC chromatogram NMR spectrum Mass spectrum MS available upon request

Application

Ethyl cinnamate is a widely used aroma chemical in the flavor and fragrance industry. It imparts sweet, fruity, and honey like notes to perfumes, soaps, and cosmetics, often used in oriental and floral compositions. As a flavoring agent, it enhances strawberry, cherry, plum, and cinnamon profiles in beverages, baked goods, and confectionery. In the polymer industry, ethyl cinnamate serves as a monomer in UV curable coatings and inks due to its reactive double bond, contributing to fast curing and good adhesion. It is also employed as a precursor for the synthesis of pharmaceutical intermediates, including certain antihypertensive and antidiabetic compounds. Additionally, it acts as a UV absorber in sunscreens and plastic additives, and as a starting material for cinnamic acid derivatives used in agrochemicals and preservatives. In academic research, it is a standard for photodimerization studies and as a model compound for transesterification reactions.

Custom Synthesis Support

We offer custom synthesis for ethyl cinnamate derivatives including substituted cinnamates, hydrogenated products, and higher purity grades (99.5 percent and above). Share your technical datasheet for feasibility review.

Packaging and Shipping

Available in 500 mL, 1 L, 5 L, 25 L HDPE drums, or 200 L steel drums. Custom packaging such as amber glass bottles with PTFE lined caps is supported. Fastest dispatch within 7 days after order confirmation. Non hazardous under normal transport, keep away from heat and oxidizers. Store in tightly closed containers protected from light.

Why XinChem

XinChem provides ethyl cinnamate with consistent organoleptic profile and high purity for US customers. Our ISO 9001 certified facility monitors every batch by GC and sensory evaluation, ensuring lot to lot reproducibility for flavor and fragrance applications. We maintain a buffer stock of 5 metric tons in US warehouses for emergency deliveries within 48 hours. Each order includes a full documentation package: COA, SDS, GC chromatograms, and NMR spectra accessible through our online portal. Our technical support team assists with stability studies, regulatory compliance including FEMA GRAS status, TSCA, and EINECS. For contract customers, we offer quarterly price locks and consignment inventory to reduce supply chain risk. Trusted by over 200 flavor houses and specialty chemical companies in North America. We also provide free sample evaluation for qualified R&D projects and a price match guarantee against any valid competitor quote for equivalent quality.

FAQ

Q1 How should ethyl cinnamate be stored to maintain its flavor profile?
A Store in a cool, dry place away from direct sunlight and strong oxidizers. Keep containers tightly sealed. Shelf life is 24 months under recommended conditions.

Q2 What purity grades do you supply?
A Standard grade is 99.0 percent by GC. We also offer 99.5 percent grade for pharmaceutical and high end fragrance applications.

Q3 Is ethyl cinnamate soluble in water?
A It is insoluble in water but miscible with ethanol, ethyl acetate, and most organic solvents.

Q4 Do you provide sample quantities for flavor evaluation?
A Yes, free samples of 100 mL are available for qualified US companies. Shipping fee applies for small quantities.

Q5 Can you supply ethyl cinnamate with customized antioxidant addition?
A Yes, we can add BHT or tocopherol upon request to extend shelf life. Please specify your requirement.

Q6 What is the typical residual solvent level?
A Residual solvents are below 50 ppm for Class 3 solvents, compliant with USP and EP guidelines.

8.Ethyl cinnamate 103-36-6 COA-1

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