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Epichlorohydrin(CAS#106-89-8)

Chemical Property:

Molecular Formula C3H5ClO
Molar Mass 92.52
Density 1.183g/mLat 25°C(lit.)
Melting Point -57 °C
Boling Point 115-117°C(lit.)
Specific Rotation(α) -1~+1°(D/20℃)(c=1,CH3OH)
Flash Point 93°F
Water Solubility 6 g/100 mL (10 ºC)
Solubility 65.9g/l
Vapor Presure 13.8 mm Hg ( 21.1 °C)
Vapor Density 3.2 (vs air)
Appearance Liquid
Specific Gravity 1.183 (20/4℃)
Color APHA: ≤20
Odor Pungent, garlic; sweet, pungent; like chloroform.
Exposure Limit TLV-TWA(skin) 8 mg/m3(2 ppm) (ACGIH);STEL (15 min) 19 mg/m3(5 ppm) (NIOSH).
Merck 14,3611
BRN 79785
Storage Condition Store below +30°C.
Stability Stability Unstable. Flammable – note wide explosion limits and low flash point. Vapours may flow along surfaces to source of ignition. Contact with strong oxidisers may lead to fire. Incompatible with
Explosive Limit 3.8-21%(V)
Refractive Index n20/D 1.438(lit.)
Physical and Chemical Properties Volatile, unstable, colorless oily liquid with chloroform-like odor.
boiling point 116.11 ℃
freezing point -57.2 ℃
relative density 1.18066g/cm3
refractive index 1.4382
flash point 40.6 ℃
solubility and most organic compounds solvent miscibility, slightly soluble in water.
Use Used as a raw material for organic synthesis, but also as a solvent, plasticizer, surfactant, etc

Product Detail

Product Tags

Hazard Symbols T - Toxic
Risk Codes R45 - May cause cancer
R10 - Flammable
R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed.
R34 - Causes burns
R43 - May cause sensitization by skin contact
Safety Description S53 - Avoid exposure - obtain special instructions before use.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
UN IDs UN 2023 6.1/PG 2
WGK Germany 3
RTECS TX4900000
TSCA Yes
HS Code 2910 30 00
Hazard Class 6.1
Packing Group II
Toxicity LD50 orally in rats: 0.09 g/kg (Smyth, Carpenter)

 

Product Name and CAS Number

Epichlorohydrin 1 Chloro 2 3 epoxypropane | CAS 106 89 8

One Line Sourcing Position

High purity Epichlorohydrin for epoxy resin production and specialty chemical synthesis.

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Specification

Purity by GC: 99.5 percent minimum, typical batch 99.7 to 99.9 percent
Appearance: Colorless clear liquid
Density at 20 deg C: 1.176 to 1.180 g per mL
Refractive index nD20: 1.435 to 1.438
Water content Karl Fischer: 0.10 percent maximum
Epoxide value: 0.95 to 1.05 equivalents per 100 g
Color APHA: 15 maximum
Residue on evaporation: 0.02 percent maximum
Heavy metals: Less than 5 ppm
Stock Status: In Stock in US warehouse and China hub

Available Quantity and Lead Time

Regular supply: 5 kg to 50 metric tons per shipment
Lead time: 3 to 5 days for standard packaging; bulk orders require 7 to 10 days

Document Support

COA SDS HPLC chromatogram NMR spectrum Mass spectrum MS available upon request

Application

Epichlorohydrin is a versatile chemical intermediate primarily used in the production of epoxy resins. It reacts with bisphenol A to form diglycidyl ethers, which are the backbone of high performance coatings, adhesives, composites, and electrical laminates. In the synthesis of synthetic glycerin, epichlorohydrin is hydrolyzed to monochlorohydrin and then to glycerol, serving as a major route for glycerin production. The compound is also a precursor for elastomers such as epichlorohydrin rubber (ECO and GECO), which offer excellent oil, fuel, and ozone resistance for automotive and industrial hoses and seals. In water treatment, epichlorohydrin is used to produce cationic flocculants by reacting with dimethylamine and ammonia, resulting in polyamine polymers that clarify raw water and treat industrial wastewater. The pharmaceutical industry employs it as an alkylating agent for synthesizing beta blockers (e.g., propranolol, atenolol) and other drugs. Additionally, epichlorohydrin is used in paper wet strength resins (polyamide epichlorohydrin resins), textile finishing agents, and ion exchange membrane manufacturing.

Custom Synthesis Support

We offer custom synthesis for epichlorohydrin derivatives including glycidyl ethers, azido epoxides, and specialty resins. Share your technical datasheet for feasibility review.

Packaging and Shipping

Available in 5 kg, 20 kg, 200 kg steel drums, or IBC totes. Custom packaging such as stainless steel containers with nitrogen overlay is supported. Fastest dispatch within 7 days after order confirmation. Epichlorohydrin is a hazardous material: Class 6.1 toxic and Class 3 flammable liquid, UN 2023, PG II. Store away from acids, bases, and metal halides. Keep cool and well ventilated.

Why XinChem

XinChem provides epichlorohydrin with strict control of epoxide value and impurities for US customers. Our ISO 9001 certified facility monitors every batch by GC and Karl Fischer analysis, ensuring consistent reactivity for epoxy resin and elastomer production. We maintain a buffer stock of 25 metric tons in US warehouses for emergency deliveries within 48 hours. Each order includes a full documentation package: COA, SDS, GC chromatograms, and NMR spectra accessible through our online portal. Our technical support team assists with handling precautions, stability in storage, and regulatory compliance including TSCA, EINECS, and FDA indirect additive regulations for food contact applications. For contract customers, we offer quarterly price locks and consignment inventory to reduce supply chain risk. Trusted by over 300 resin manufacturers and water treatment companies in North America. We also provide free sample evaluation for qualified R&D projects and a price match guarantee against any valid competitor quote for equivalent quality.

FAQ

Q1 How should epichlorohydrin be stored safely?
A Store in a cool, dry, well ventilated area away from ignition sources, strong acids, bases, and metal halides. Keep container tightly sealed. Shelf life is 12 months under recommended conditions due to slow epoxide ring opening.

Q2 What purity grades do you supply?
A Standard grade is 99.5 percent minimum. We also offer 99.9 percent grade for high performance resins and pharmaceutical intermediate applications.

Q3 Is epichlorohydrin soluble in water?
A Slightly soluble in water (about 6 g per 100 mL at 20 deg C) and miscible with most organic solvents such as acetone, toluene, and dichloromethane.

Q4 Do you provide sample quantities for formulation development?
A Yes, free samples of 1 kg are available for qualified US companies. Shipping fee applies for small quantities due to hazardous material classification.

Q5 What are the common impurities in epichlorohydrin and how do you control them?
A Key impurities include 1,3 dichloro 2 propanol and 2,3 dichloro 1 propanol. Our process limits each below 0.10 percent by GC. Full impurity profiles are provided with each certificate.

Q6 Can you supply epichlorohydrin with stabilized inhibitors?
A Yes, we can add inhibitors such as nitroalkanes or tertiary amines to suppress polymerization during long term storage. Please specify your requirements.

Epichlorohydrin 106-89-8 COA-1


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